Soil organic matter

Restoring soil carbon can reverse global warming

Restoring soil carbon can reverse global warming
Erich J. Knight, February 21, 2008

Here is a strait forward conversion of the impact of building soil organic material (SOM) on ppm of GHGs using just marginal land.

http://news.mongabay.com/2008/0221-soil_carbon_lovell_interview.html

Tony Lovell of Soil Carbon P/L in Australia estimates that by actively supporting regrowth of vegetation in damaged ecosystems, billions of tons of carbon dioxide can be sequestered from the atmosphere.

"Determining how much carbon dioxide (CO2) can physically be consumed from the atmosphere?

As the planet has 7.8 billion tonnes of carbon dioxide in circulation for each 1 ppm of atmospheric CO2, and there are 5 billion hectares of inappropriately managed or unmanaged, desertifying savannahs on the Earth (which on empirical evidence we contend to be the case), the question that should sensibly be asked is: How much carbon dioxide would be absorbed if policies were put in place (in Australia and elsewhere) that caused the focus of on-ground management to be deliberately directed towards the widespread consumption of cyclical GHGs within the currently under-utilised savannah lands?

Consumption of CO2 per hectare
• One hectare is 10,000 sq. metres. If a hectare of soil 33.5 cm deep, with a bulk density of 1.4 tonnes per cubic metre is considered, there is a soil mass per hectare of about 4,700 tonnes.
• If appropriate management practices were adopted and these practices achieved and sustained a 1% increase in soil organic matter (SOM)6, then 47 tonnes of SOM per hectare will be added to organic matter stocks held below the soil surface
• This 47 tonnes of SOM will contain approximately 27 tonnes of Soil Carbon (ie 47 tonnes at 58% Carbon) per hectare
• In the absence of other inputs this Carbon may only be derived from the atmosphere via the natural function known as the photo-synthetic process. To place approximately 27 tonnes of Soil Carbon per hectare into the soil, approximately 100 tonnes of carbon dioxide must be consumed out of the atmosphere by photosynthesis
• A 1% change in soil organic matter across 5 billion hectares will sequester 500 billion tonnes of physical CO2
Converting global Soil Carbon capacity to ppm of atmospheric GHGs
1. Every 1% increase in retained SOM within the topmost 33.5 cm of the soil must capture and hold approximately 100 tonnes per hectare of atmospheric carbon dioxide (the variability in the equation being due only to the soil bulk density). We submit that under determined, appropriate management, that this is readily achievable within a very few years
2. For each 1% increase in SOM achieved on the 5 billion hectares there will be removed 64 ppm of carbon dioxide from atmospheric circulation (500,000,000,000 tonnes CO2 / 7,800,000,000 tonnes per ppm = 64 ppm).
3. Soil Organic Matter is the plant material released into the soil during the natural phases of plant growth. It includes root material sloughed off below the soil surface and plant litter carried into the soil by microbes, insects and rainfall
4. Soil Carbon is the elemental carbon contained within Soil Organic Matter (SOM).
5. One tonne of CO2 contains 12/44 units of carbon (ie 0.27 tonnes of carbon per tonne of CO2.). Therefore 27 tonnes of carbon sequesters 27/0.27 = 100 tonnes CO2 (rounded). NB Carbon atomic weight 12, oxygen atomic weight 16 ie CO2 = 12+(16+16) = 44
The global opportunity and numbers

It appears that the pre-industrial level of atmospheric carbon dioxide was 280ppm, and that globally we are now at 455ppm, and heading towards 550ppm. To get from 550ppm back to 280ppm, 270ppm must be removed. Globally, a 4.2% increase in SOM would potentially reverse the expected situation. In any case, any form of determined management will substantially reduce the now crippling legacy loadings in the atmosphere.

Erich J. Knight
1047 Dave Berry Rd.
McGaheysville, VA. 22840
540-289-9750
shengar@aol.com


Research Project: Biogeochemical Processes Influencing Formation and Stabilization of Soil Organic Matter and Soil Structure

Research Project: Biogeochemical Processes Influencing Formation and Stabilization of Soil Organic Matter and Soil Structure
National Soil Tilth Laboratoryi, USDAi Agricultural Research Service, Ames, IA
Location: Soil and Water Quality Research
Project Number: 3625-11120-003-00
Project Type: Appropriated
Start Date: Apr 25, 2006
End Date: Apr 24, 2011
Objective:
1)Develop a mechanistic understanding of processes controlling the formation and stabilization of organic matter in soils that enhance stabilization of soil structure. a) Determine the relative contributions of biochemical compounds to aggregation and C sequestration. b) Determine the role of clay minerals and charcoal in the formation and stabilization of soil organic matter and soil structure. c) Determine the nature of reactions between smectites and pesticides. d) Determine the effects of anaerobic soil conditions on biochemical processes that influence soil nutrient cycling. e) Develop integrative methods for fractionating SOM into meaningful pools. 2) Develop tools for in situ assessment of soil organic carbon and soil structure. a) Develop a multi-function probe (electrical and thermal properties) to evaluate soil structure. b) Develop and evaluate a field mobile NIRS tool for sensing soil carbon and various soil properties.
Approach:
Field plot and column leaching studies will be used to quantify the impact of adding charcoal to soils on nutrient cycling, soil productivity, C sequestration, pesticide leaching, and on the formation and stabilization of clay-humic complexes. Interactions between selected pesticides and reference clays will be investigated to elucidate bonding mechanisms between organic molecules and clay surfaces. Seasonal patterns for cycling of phenolic and organic nitrogen compounds will be compared for routinely flooded and non-flooded soils. Anticipated products will include more accurate predictions of how crop and soil management effect nutrient cycling and soil organic matter stabilization. We will develop and test electrical and thermal soil probes to characterize soil structure. A regional non-linear multivariate calibration model for a recently developed on-the-go in situ near infrared diffuse reflectance soil probe will be evaluated to determine if the system can accurately map the spatial distribution of numerous soil properties (organic C, total N, CECi, moisture, buffer pH, and extractable nutrients) at the field scale.


Soil Organic Carbon

Soil Organic Carbon
Jan Skjemstad, CRC Greenhouse Accounting

In Summary

Soil OC is a significant source and sink of atmospheric CO2

Soil is a complex, biologically active medium

Soil OC is not one material

Changes in SOC can be measured directly or can be modelled

The C sink value of soils is limited BUT increasing and maintaining SOC has many benefits for improved productivity and soil resilience


Manage carbon to sustain soil structure

Manage carbon to sustain soil structure
Jan Skjemstad, CSIRO LAND AND WATER AND CRC FOR GREENHOUSE ACCOUNTING in FARMING AHEAD No. 158 March 2005

Soil organic carbon plays a critical role in the biological, chemical and physical health of a soil. But little is known about how crop management impacts on soil organic carbon levels and thus soil health. This article describes how a new approach to understanding this relationship could help farmers better manage soil organic carbon.


Exploring Atypical Stabilization Pathways Using Pool-Based Modeling

Exploring Atypical Stabilization Pathways Using Pool-Based Modeling
Sohi, Saran, Yates, Helen, Lehmann, Johannes Liang, Biqing, Gaunt, John
Cornell University WCSS Poster 2006

Simulation models that explicitly account for the impact and interaction of soil and environmental variables can assist in predicting the accumulation of C and its rate of turnover. Relevant, verifiable (i.e. measurable) pools of Soil Organic Matter (SOM) provide the most robust basis for elucidating the underlying mechanisms. We have developed a model based around three measurable pools of SOM which can be measured using a density-based fractionation procedure, and verified by extensive chemical characterization. The model has been optimized against measurements of C and N and isotope-tracers in several soils amended with isotope-labeled organic matter. According to recent estimates black C is a much larger component of Soil Organic Carbon (SOC) in typical agricultural soils than previously assumed. Since black C may also be the most stable form of organic C in the soil, the amount of black C in the soil must impact both on the bulk rate of soil C mineralization (turnover) and the extent to which a particular management intervention can alter SOC. Until now our simulations have not accounted explicitly for the effect of black C on the dynamics of each pool. We are now examining how black C is characterized by physical location within the soil matrix, and in order to account for the influence of black C using this model affects C mineralization, and the distribution of charcoal between each of the measured fractions.


Soil erosion, energy scarcity, excess greenhouse gas all answered through regenerative carbon management

Soil erosion, energy scarcity, excess greenhouse gas all answered through regenerative carbon management
Paul Hepperly, The New Farm, Rodale Institutei, January 12, 2006

Composti is great, but new bio-based process yields hydrogen and super-stable carbon as charcoal soil booster.


Black Carbon Increases Cation Exchange Capacity in Soils

Black Carbon Increases Cation Exchange Capacity in Soils
Liang et al. Soil Sci Soc Am J.2006; 70: 1719-1730

Authors:
B. Liang, J. Lehmann, D. Solomon, J. Kinyangi, J. Grossman, B. O'Neill, J. O. Skjemstad, J. Thies, F. J. Luizão, J. Petersen and E. G. Neves

Abstract:

Black Carbon (BC) may significantly affect nutrient retention and play a key role in a wide range of biogeochemical processes in soils, especially for nutrient cycling. Anthrosolsi from the Brazilian Amazon (ages between 600 and 8700 yr BP) with high contents of biomass-derived BC had greater potential cation exchange capacity (CECi measured at pH 7) per unit organic C than adjacent soils with low BC contents. Synchrotron-based near edge X-ray absorption fine structure (NEXAFS) spectroscopy coupled with scanning transmission X-ray microscopy (STXM) techniques explained the source of the higher surface charge of BC compared with non-BC by mapping cross-sectional areas of BC particles with diameters of 10 to 50 µm for C forms. The largest cross-sectional areas consisted of highly aromatic or only slightly oxidized organic C most likely originating from the BC itself with a characteristic peak at 286.1 eV, which could not be found in humic substance extracts, bacteria or fungi. Oxidation significantly increased from the core of BC particles to their surfaces as shown by the ratio of carboxyl-C/aromatic-C. Spotted and non-continuous distribution patterns of highly oxidized C functional groups with distinctly different chemical signatures on BC particle surfaces (peak shift at 286.1 eV to a higher energy of 286.7 eV) indicated that non-BC may be adsorbed on the surfaces of BC particles creating highly oxidized surface. As a consequence of both oxidation of the BC particles themselves and adsorption of organic matter to BC surfaces, the charge density (potential CEC per unit surface area) was greater in BC-rich Anthrosols than adjacent soils. Additionally, a high specific surface area was attributable to the presence of BC, which may contribute to the high CEC found in soils that are rich in BC.


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